No it will not change the trany behavior
The power of the motor is not really a issue with the shift strategy of the transmission...
Your Smart fortwo transmission is a 5 speed computer controlled manual transmission that does the clutch work with an electric motor pretending to be your left clutch foot .....it is behaving exactly like any standard manual transmission
To change a gear up or down, the clutch must be disengaged, the shift happen, then clutch released to re-engage...this will always have some noticeable (lag) time during shifts.
When the modification kits get to us here in the USA, we should be able to increase the 1.0 L motor from 71 HP to 84~95HP fairly easily... but this will not make the manual trany feel more like a smooth as silk automatic in other Mercedes products...