the cooler days is inconsistent with my suggestion that you bleed the head for air in the coolant, but I would do that anyway just to eliminate that as a possibility. My knock went away when I eliminated an air pocket in the engine. Two different smart centers could not figure that out. The first one said I had a tank of bad gas. The second one said We don't know. You need to drive eight hours to another dealer with more technology to figure it out.
I used Water Wetter in the engine and had to top off the reservoir two more times and been okay ever since. It apparently absorbed the air and got it to the reservoir.
This may not be your issue, but if you have a hot spot, the water wetter may solve that for you, also.
A third alternative is to replace your coolant with a much higher boiling point waterless coolant. Evans makes such a thing.
Here is a very informative list of FAQ's on their site that addresses hot spots, water pump cavitation, and micro nucleation. Very informative reading:
http://www.evanscoolants.com/evans_waterless_engine_coolants_faqs.html